process plant

SPOCC Reactor

Carbon is an essential element for living animals and plants, but atmospheric carbon dioxide levels need to be controlled. The greenhouse effect is explained here. It is better to re-use the carbon than expend energy trying to bury it.

Omnagen’s SPOCC (Self-powered CO2 Converter) Reactor converts methane, carbon dioxide and air into syn gas: converting CO2 into useful chemicals. No heat or electricity is required, as the energy is derived from the chemical energy in methane, and there are no waste gases. This process has a negative carbon footprint, and allows the sustainable use of fossil fuels. Patents have been applied for.

fuel cell and electrolyser

It works by combining a fuel cell which produces syngas and electricity, with an electrolyser which consumes electricity and produces more syngas. Syngas is a mixture of carbon monoxide and hydrogen. The syngas can be further converted to liquid and solid chemicals by conventional chemical processing techniques.

converter reactions

There are 3 reactions:-

Fuel cell:- CH4 + ½O2 = CO + 2H2 + electricity + some heat

Electrolyser:- electricity + heat + CH4 + CO2 = 2CO + 2H2

Direct:- 2CH4 + O2 = 2CO + 4H2 + heat

Overall:- 2CH4 + CO2 + ½O2 = 3CO + 4H2

The controlled direct reaction provides heat to counter the endothermic reactions, and also helps to prevent carbon deposition at the electrodes.

This converter uses solid oxide cells, and the real innovation is how to combine these two components into a simple self-powered unit. The solution is to provide one gas flow which is a mixture of gases, and another which provides oxygen or air. The electrical connections are direct, and this also allows heat from exothermic anode reactions to transfer to cathodes on adjacent cells where the reactions are endothermic. The overall reaction rate is controlled by the oxygen supply.

As the invention involves the manipulation of gas flows, it should be very scalable. At the large scale it could be used to provide raw material for bulk chemicals and polymers. At the small scale it could be used in conjunction with small scale FT plants to produce eFuels for local consumption.

The electrolyser component may be used separately to convert a flow of carbon dioxide and methane, providing there is also a supply of electricity and air or oxygen. Conventional electrolysis of carbon dioxide and steam requires a great deal of energy, but the reaction of carbon dioxide and methane is more thermodynamically favoured, so it requires much less energy.

Some possible applications:-

  • Complementing SMR (steam methane reforming) which produces syngas and lots of CO2. The CO2 can be combined with methane to produce more syngas
  • Biogas is a mixture of methane and carbon dioxide. This can be converted to syngas, and then further to a range of liquid and solid chemicals.
  • Natural gas extracted in remote locations has to be coverted to liquid for transportation. It often contains alot of carbon dioxide.

GB and PCT patent applications have been filed. The GB application numbers are as follows:-

  • CO2 converter - GB2568564. This application has now been granted, grant date 1st January 2020.
  • Chemical reactor - GB2568563

There is a range of carbon re-use technologies under the title ‘Power-to-X’. These use a great deal of electricity, and are carbon neutral providing that electricity originates from renewable sources. This has the inherent problems of intermittent supplies, and whether enough renewable energy is available to deal with the scale of the problem.

Please contact Ken Omersa if you'd like more information; phone and email details are provided here.